微球
催化作用
ZSM-5型
多孔性
材料科学
化学工程
化学
核化学
沸石
复合材料
有机化学
工程类
作者
Zhengzhong Cheng,Qian Zhang,LI Zhi-fang,Jinxing Cui,Jiao Zhao,Ruichao Yang,Yuan‐Yuan Ma,Zhen Zhang,Qi Zhao Wang,Changlong Yang
标识
DOI:10.1002/slct.202401052
摘要
Abstract Microporous zeolite is commonly employed as the catalyst for selective catalytic reduction of NO x using NH 3 as reducing agent (NH 3 ‐SCR) because of its strong acidity and exceptional hydrothermal stability. However, the channel of microporous zeolite limits mass transfer under low temperature. Hierarchical porous molecular sieves can overcome the above imperfections. Hierarchical pore (microporous/mesoporous/macroporous) ZSM‐5 molecular sieves were prepared using polystyrene(PS) microspheres with different particle size as the hard templates and then the ion exchange method was utilized to introduce the active components Ce, Cu, and La. In addition, the effect of PS microspheres with different size and H 2 O+SO 2 on denitrification performance was also investigated. The results exhibited that the specific surface area of the hierarchical pore ZSM‐5 was the smallest when the size of polystyrene microspheres was the largest. The NO x conversion of all supported hierarchical porous catalysts is more than that of supported microporous ZSM‐5 catalyst in the low temperature (200 °C), which was because that the presence of the mesopores favored diffusion‐control in the low temperature, expediting the reactant transport. Furthermore, the supported hierarchical pore ZSM‐5 catalyst exhibited excellent denitrification performance in a wide temperature range of 250–500 °C (the conversion of NO x exceeded 80 % and the N 2 selectivity was approaching 100 %). More importantly, the supported hierarchical pore ZSM‐5 catalyst demonstrated notably superior water and SO 2 resistance in comparison to the supported micropore ZSM‐5 catalyst.
科研通智能强力驱动
Strongly Powered by AbleSci AI