Mechanical and thermal properties of rice husk/glass fiber/polylactic acid composites

材料科学 去壳 聚乳酸 复合材料 热稳定性 热重分析 复合数 极限抗拉强度 傅里叶变换红外光谱 扫描电子显微镜 纤维 聚合物 化学工程 生物 植物 工程类
作者
Yufeng Sun,Ziheng Zhang,Jinwei Wang,Hengyu Liu,Dongming Shi,Mingyang Liu,Jilai Ying,Wenlong Mu,Defeng Li,Song Wu
出处
期刊:Polymer Composites [Wiley]
标识
DOI:10.1002/pc.28876
摘要

Abstract Polylactic acid (PLA) composites reinforced with rice husk and glass fiber can improve the properties in the aera of the material for vehicle application. In this work, the PLA composite was made and its properties were evaluated using scanning electron microscope (SEM), Fourier transform infrared spectroscopy (FTIR), and thermogravimetric analysis (TGA). SEM observed that the polymer matrix contained a uniform dispersion of 10 wt% rice husks. The tensile strength and bending strength of the composite are 45.8 and 48.2 MPa, respectively, which are 52% and 41% higher than that of the base material PLA. TGA revealed that the thermal stability of the composite deteriorated with increasing rice husk content. The DTG curve indicated that the incorporation of rice husk and glass fiber led to a reduction in the maximum degradation rate of the PLA matrix. As a result, the thermal degradation of the PLA composite exhibited enhanced stability. The average apparent activation energy (Ea) of the composite, determined using the Friedman (FD), Flynn Wall Ozawa (FWO), Starink (ST), and Kissinger (KS) models, falls within the range of 90 to 120 kJ mol −1 . Highlights Silane coupling agent was used to improve the interfacial compatibility of fillers. The synergistic action of rice husk and glass fiber fillers enhances the mechanical properties of polylactic acid composites. The mean apparent activation energy (Ea) of the composite was calculated using four models, with values in the range of 90 to 120 kJ mol −1 . The Flynn Wall Ozawa and Starink models showed better stability against temperature changes compared to the Friedman model.
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