Efficient Inverted Perovskite Photovoltaics Through Surface State Manipulation

Abstract Inverted perovskite solar cells (PSCs) are considered as the most promising avenue for the commercialization of PSCs due to their potential inherent stability. However, suboptimal interface contacts between electron transport layer (ETL) (such as C 60 ) and the perovskite absorbing layer within inverted PSCs always result in reduced efficiency and poor stability. Herein, a surface state manipulation strategy has been developed by employing a highly electronegative 4‐fluorophenethylamine hydrochloride ( p ‐F‐PEACl) to effectively address the issue of poor interface contacts in the inverted PSCs. The p ‐F‐PEACl demonstrates a robust interaction with perovskite film through bonding of amino group and Cl − with I − and Pb 2+ ions in the perovskite, respectively. As such, the surface defects of perovskite film can be significantly reduced, leading to suppressed non‐radiative recombination. Moreover, p ‐F‐PEACl also plays a dual role in enhancing the surface potential and improving energy‐level alignment at the interfaces between the perovskite and C 60 carrier transport layer, which directly contributes to efficient charge extraction. Finally, the open‐circuit voltage ( V oc ) of devices increases from 1.104 V to 1.157 V, leading to an overall efficiency improvement from 22.34% to 24.78%. Furthermore, the p ‐F‐PEACl‐treated PSCs also display excellent stability.