Controlling Nucleation and Crystallization of CsPbI3 Perovskites for Efficient Inverted Solar Cells

Abstract The unfavorable morphology and high crystallization temperature ( T c ) of inorganic perovskites pose a significant challenge to their widespread application in photovoltaics. In this study, an effective approach is proposed to enhance the morphology of cesium lead triiodide (CsPbI 3 ) while lowering its T c . By introducing dimethylammonium acetate into the perovskite precursor solution, a rapid nucleation stage is facilitated, and significantly enhances the crystal growth of the intermediate phase at low annealing temperatures, followed by a slow crystal growth stage at higher annealing temperatures. This results in a uniform and dense morphology in CsPbI 3 perovskite films with enhanced crystallinity, simultaneously reducing the T c from 200 to 150 °C. Applying this approach in positive‐intrinsic‐negative (p‐i‐n) inverted cells yields a high power conversion efficiency of 19.23%. Importantly, these cells exhibit significantly enhanced stability, even under stress at 85 °C.