Impacts of wet-dry alternations on cadmium and zinc immobilisation in soil remediated with iron oxides

Chemical immobilisation is extensively used for in-situ remediation of heavy metals contaminated soil. Immobilised heavy metals could be reactivated by multiple factors such as pH, moisture, temperature, rainfall, etc., among which rainfall is very important, especially acid rain in southern China. Wet-dry alternations were used to simulate the leaching of metals by rainwater. The variation of cadmium (Cd) and zinc (Zn) speciation distribution in soil immobilised with iron oxides (goethite (GE) and 2-line ferrihydrite (GLS)) was investigated. The impacts of wet-dry alternations on the properties of the soil and amendments were also assessed. In the soil without amendments (OS) and amended with GE (GS), the stable fractions were reactivated and transformed into labile fractions under wet-dry alternations. In the soil amended with GLS (LS), the exchangeable and carbonate-bound Cd decreased while the soluble, Fe-Mn oxide bound and organic bound Cd increased. The carbonate-bound Zn was transformed into the Fe-Mn oxide-bound Zn. Transformation from the amorphous iron oxide into crystalline iron oxide in GS and LS were 4.9% and 5.3%. The Pearson correlation analysis showed that the soil pH and the iron-oxide speciation were strongly correlated with Cd/Zn fractions in the soil. The specific surface area, pore volume and adsorption capacity of the iron oxides decreased by 9.26%, 38.89% and 62-73% (for GE), 1.88%, 22.22% and 26-55% (for GLS). The altered soil properties and morphological differences between the two iron oxides under wet-dry alternations were important reasons for Cd/Zn reactivation.