光催化
异质结
材料科学
固氮
制作
氮气
纳米技术
可见光谱
化学工程
化学
光电子学
催化作用
医学
有机化学
病理
工程类
替代医学
生物化学
作者
Chuhan Huang,Yu Ma,Cheng Qian,Xiaohan Liu,Hongman Sun,Fazle Subhan,Xinyuan Zhao,Youhe Wang,Zifeng Yan
标识
DOI:10.1016/j.apsusc.2024.159952
摘要
The fundamental insights into the reaction mechanism, especially the electron transfer mechanism, are highly promising yet challenging for W18O49/g-C3N4 heterojunction catalysts during photocatalytic nitrogen fixation. Herein, the 1D/2D nanostructured S-scheme heterojunctions were designed by in situ growth of 1D W18O49 nanowires on 2D g-C3N4 nanosheets through solvothermal method using methanol as solvent. In situ, XPS analysis revealed that electrons in the conduction band of W18O49 recombine with holes in the valence band of g-C3N4 under the conduction effect of internal electric field, band bending, and Coulombic attraction in the W18O49/g-C3N4 heterojunction. The photogenerated electrons are retained in g-C3N4, where the negative reduction potential of its conduction band enhances the activation of N2. As a result, the ammonia generation rate employing the optimal W18O49/g-C3N4 heterojunction is 64.8 μmol gcat−1 h−1, approximately double that of W18O49 alone and 2.3 times higher than that of g-C3N4. The enhanced activity and facile methodology make the current material exceedingly appealing for implementation in photocatalytic nitrogen fixation for the synthesis of ammonia.
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