材料科学
阳极
碳纳米管
锂(药物)
纳米颗粒
电池(电)
锂离子电池
电解质
电化学
纳米技术
碳纤维
化学工程
复合材料
复合数
电极
物理化学
医学
功率(物理)
化学
物理
量子力学
内分泌学
工程类
作者
Zifan Wang,Jiaxu Qi,Han Li,Ying Wang,Qingli Liu,Zhen Kong,Xing Gao,Jiajia Ye,Qian Liu,Yang Chen,Guang Xia
标识
DOI:10.1016/j.matlet.2024.136332
摘要
CoS2 nanoparticles are effectively incorporated into N-doped hollow carbon nanotubes (CoS2@HC) through a combination of a straightforward oil bath method and a high-temperature sulfurization process. The CoS2@HC composite demonstrates exceptional electrochemical performance as an anode material in Li-ion batteries. The outstanding performance of this system can be attributed to the ingeniously designed hollow carbon nanotubes. These nanotubes not only possess high electrical conductivity, thus facilitating efficient electron transfer, but also provide ample space to accommodate volume changes. Furthermore, the ultrafine CoS2 nanoparticles embedded within the hollow carbon nanotubes offer a large surface area for effective electrolyte wetting and rapid ion diffusion during the cycling process. As a result, the CoS2@HC composite delivers a high capacity of 356.2 mAh·g−1 at 2000 mA·g−1 even after 1500 cycles, demonstrating remarkable cyclic stability.
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