醇盐
配体(生物化学)
化学
金属有机骨架
金属
桥联配体
催化作用
结晶学
无机化学
有机化学
生物化学
吸附
受体
作者
Sumin Yu,N. D. Kim,Jong Hyeak Choe,Hyo‐Jin Kim,Dae Won Kim,Jeongwon Youn,Yong Hoon Lee,Chang Seop Hong
标识
DOI:10.1002/anie.202400855
摘要
Postsynthetic modifications (PSMs) of metal-organic frameworks (MOFs) play a crucial role in enhancing material performance through open metal site (OMS) functionalization or ligand exchange. However, a significant challenge persists in preserving open metal sites during ligand exchange, as these sites are inherently bound by incoming ligands. In this study, for the first time, we introduced alkoxides by exchanging bridging chloride in Ni
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