Series of Viologen-Based Metal–Organic Polyhedra with Photo/Electrochromic Behavior for Inkless Printing and UV Detection

The fabrication of molecular crystalline materials with fast, multistimuli-responsive behavior and the construction of the corresponding structure–activity relationship are of extraordinary significance for the development of smart materials. In this context, three multistimuli-responsive functional metal–organic polyhedra (MOP), {[Dy2(bcbp)3(NO3)1.5(H2O)7]·Cl4.2·(NO3)0.3·H2O}n (1), {[Dy2(bcbp)4(H2O)8]Cl6}n (2), and {[Eu2(bcbp)4(H2O)10]Cl6·H2O}n (3; bcbp = 1,1′-bis(4-carboxyphenyl)-4,4′-bipyridinium), were successfully prepared and characterized. All of the compounds exhibit rapid and reversible photochromic and electrochromic dual-responsive behaviors. Furthermore, benefiting from the well-defined crystal structure and different responsive behaviors, the photoinduced electron transfer (PIET) process and structure–activity relationship were explored. In addition, considering the excellent photochromic performance, function filter paper and smart organic glass were successfully prepared and used for ink-free printing and UV light detection.