Bioinspired Superhydrophobic Fibrous Materials

Abstract Natural fibers with robust water repellency play an important role in adapting organisms to various environments, which has inspired the development of artificial superhydrophobic fibrous materials with applications in self‐cleaning, antifogging, water harvesting, heat exchanging, catalytic reactions, and microrobots. However, these highly textured surfaces (micro/nanotextured) suffer from frequent liquid penetration in high humidity and abrasion‐induced destruction of the local environment. Herein, bioinspired superhydrophobic fibrous materials are reviewed from the perspective of the dimension scale of fibers. First, the fibrous dimension characteristics of several representative natural superhydrophobic fibrous systems are summarized, along with the mechanisms involved. Then, artificial superhydrophobic fibers are summarized, along with their various applications. Nanometer‐scale fibers enable superhydrophobicity by minimizing the liquid–solid contact area. Micrometer‐scale fibers are advantageous for enhancing the mechanical stability of superhydrophobicity. Micrometer‐scale conical fibrous structures endow a Laplace force with a particular magnitude for self‐removing condensed tiny dewdrops in highly humid air and stably trapping large air pockets underwater. Furthermore, several representative surface modification strategies for constructing superhydrophobic fibers are presented. In addition, several conventional applications of superhydrophobic systems are presented. It is anticipated that the review will inspire the design and fabrication of superhydrophobic fibrous systems.