Engineering Metal–Phenolic Networks for Solar Desalination with Directional Salt Crystallization

Abstract Solar desalination is one of the most promising strategies to address the global freshwater shortage crisis. However, the residual salt accumulated on the top surface of solar evaporators severely reduces light absorption and steam evaporation efficiency, thus impeding the further industrialization of this technology. Herein, a metal–phenolic network (MPN)‐engineered 3D evaporator composed of photothermal superhydrophilic/superhydrophobic sponges and side‐twining hydrophilic threads for efficient desalination with directional salt crystallization and zero liquid discharge is reported. The MPN coatings afford the engineering of alternating photothermal superhydrophilic/superhydrophobic sponges with high heating efficiency and defined vapor escape channels, while the side‐twining threads induce site‐selective salt crystallization. The 3D evaporator exhibits a high and stable indoor desalination rate (≈2.3 kg m −2 h −1 ) of concentrated seawater (20 wt%) under simulated sun irradiation for over 21 days without the need for salt crystallization inhibitors. This direct desalination is also achieved in outdoor field operations with a production rate of clean water up to ≈1.82 kg m −2 h −1 from concentrated seawater (10 wt%). Together with the high affinity and multiple functions of MPNs, this work is expected to facilitate the rational design of solar desalination devices and boost the research translation of MPN materials in broader applications.