Anodization-Processed Colored Radiative Thermoregulatory Film

Colored radiative thermal management materials (RTMM) not only provide superior thermoregulatory performance but also satisfy aesthetic requirements. However, the complexity of the preparation procedures and constrained color selection have hindered their widespread adoption. Here, we presented a facile one-step anodizing strategy for fabricating colored dual-mode RTMM based on titanium film (Ti) and P(VDF-HFP) with mid-infrared (MIR) emissivities of 0.07 and 0.96, respectively, which allow for on-demand temperature modulation (rise of 28.2 K and drop of 9 K) without energy consumption. Furthermore, demonstrations of a colored radiative warming membrane also validate the effectiveness of anodizing treatment. The colored Ti/nano PE membrane with 10.8 μm thickness enables a temperature rise of 2.3 K on real human skin, which is much higher than that of commercial fabric with 120 μm thickness (0.7 K). This strategy provides insights for the scalable fabrication and application of colored low emissivity materials, contributing to the goal of a sustainable society.