A Remarkable Pt Doped CNT Catalyst as a Double Functional Material: Its Application for Hydrogen Production and Supercapacitor

超级电容器 制氢 催化作用 材料科学 兴奋剂 生产(经济) 纳米技术 化学工程 化学 光电子学 电极 电容 有机化学 工程类 经济 物理化学 宏观经济学
作者
Tülin Avcı Hansu
标识
DOI:10.21926/cr.2402005
摘要

In this study, by producing bifunctional material, hydrolysis, and supercapacitor applications were investigated. The carbon nanotube-supported Pt catalyst was prepared using the sodium borohydride (NaBH<sub>4</sub>) reduction. Surface characterization of the synthesized Pt/CNT catalyst was performed using scanning electron microscopy-energy dıstrıbutıon X-ray spectrometer (SEM-EDX), X-ray diffraction (XRD), and transmission electron microscopy (TEM). Hydrolysis experiments were performed after deciding on the appropriate atomic ratio from the Pt/CNT catalysts synthesized in different nuclear ratios. The parameters affecting the hydrogen production from NaBH<sub>4</sub> were examined. As a result of the kinetic calculations, the initial rates of reaction for 30°C and 60°C were calculated as 21949,69 mlH<sub>2</sub>g<sub>cat</sub>min<sup>-1</sup> and 70018,18 mlH<sub>2</sub>g<sub>cat</sub>min<sup>-1</sup>. Galvastonic charge-discharge (GCD), cyclic voltammetry (CV), and electrochemical impedance spectroscopy (EIS) were used as characterization techniques for the use of Pt/CNT catalysts as electrodes in supercapacitor applications. The specific capacitance value of 7% Pt/CNT catalyst at 1 A/g current density was calculated as 57,78 F/g. Energy and power density were calculated as 8,025 Wh/kg and 963 W/kg, respectively. Therefore, this catalyst is called a “cap-cat” with capacitor properties. The catalyst used in this study is promising for this recently studied topic.

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