液化
废物管理
天然橡胶
烧焦
放射性废物
体积热力学
环境科学
混合废物
燃烧
化学
制浆造纸工业
材料科学
有机化学
工程类
物理
量子力学
作者
Sung‐Wook Kim,Maengkyo Oh,Min Ku Jeon
出处
期刊:Research Square - Research Square
日期:2023-11-08
标识
DOI:10.21203/rs.3.rs-3501974/v1
摘要
Abstract The accumulation of dry active wastes (DAWs) such as latex gloves in nuclear facilities has become a serious issue because of the high cost and limited storage area for their management. In this study, the liquefaction of latex gloves, which mainly comprise rubber and CaCO 3 , was investigated as a waste reduction technique. When liquefaction occurred at > 270°C, the latex gloves decomposed into gaseous, liquid, and solid products. Cs-, Sr-, and Co-contaminated latex gloves were liquefied at 350°C, and the solid product was subsequently recovered via distillation. Notably, the contaminants comprising CaCO 3 and char only remained in the solid product (~ 33.3 wt.%); thus, the gaseous and liquid products could be regarded as non-radioactive, thereby reducing the volume of radioactive waste (~ 92.7% reduction after compression). Liquefaction is favorable compared to conventional combustion because it generates less harmful gases by converting the organic components to condensed phases.
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