非阻塞I/O
催化作用
镍
化学工程
热解
材料科学
纳米颗粒
氢
制氢
比表面积
部分氧化
纳米技术
化学
冶金
有机化学
工程类
作者
Hongyu Ma,Yong Liu,Rui Xiong,Jianhong Wei
标识
DOI:10.1016/j.cclet.2021.08.048
摘要
To obtain a high-performance heterogeneous photo-catalyst, herein, the hetero-structured ZnIn2S4[email protected] (ZNM) nano-sheets are designed and prepared by partial pyrolysis of nickel-based MOFs (Ni-MOF) combined with the low-temperature solvo-thermal method. The results indicate that the NiO nanoparticles, produced by partial pyrolysis of the Ni-MOF, have a high density of the surface active sites with limited aggregation, which act as a co-catalyst to capture photo-induced charge carriers. In addition, the morphology and structure of Ni-MOF nano-sheets were preserved in ZNM, which is beneficial to the reduction of the conduction barrier for the photo generated electron-hole pairs. With the synergetic advantages of co-catalyst and unique two-dimensional hetero-structure, ZNM nano-sheets exhibited significantly improved activity for photo-catalytic hydrogen production.
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