材料科学
环氧树脂
氮化硼
复合材料
消散
硼
热力学
物理
有机化学
化学
作者
Shaojian He,Chumeng Luo,Youzhe Zheng,Xue Yang,Xupeng Song,Jun Lin
标识
DOI:10.1016/j.matlet.2021.130009
摘要
• Introduction of amino modified boron nitride nanosheets into epoxy resin. • Uniform filler dispersion and good filler-matrix compatibility. • Improved charge dissipation performance by changing the trap characteristics. To restrain the surface charge accumulation of the epoxy resin (EP) applied in the high-voltage power field, one of the efficient methods is to dissipate the charges on the EP surface by incorporating inorganic filler. In this work, we employed amine-functionalized boron nitride nanosheets (mBNNS) based on liquid-phase exfoliation and urea modification to prepare EP composites. Owing to the existence of –NH 2 groups on the exfoliated mBNNS platelets, the uniform filler dispersion and good filler-matrix compatibility were achieved in the EP composites. As compared to the pure EP, the EP/mBNNS composites exhibited better charge dissipation performance, comparable dielectric constant and higher breakdown strength. The best charge dissipation performance was achieved in the EP composite by adding only 1.0 wt% mBNNS with the surface potential decreased by 65.5% in 1200 s, much higher than pure EP (28.1%).
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