脱氢
乳酸
催化作用
氧化磷酸化
化学
丙酮酸
相(物质)
氧气
无机化学
离子
核化学
有机化学
生物化学
细菌
生物
遗传学
标识
DOI:10.1016/s0926-860x(97)00227-5
摘要
Oxidative dehydrogenation of lactic acid to pyruvic acid was performed at 230°C over iron phosphates, with a P/Fe atomic ratio of 1.2, consisting of different structures and oxidation states: these included FePO4, Fe2P2O7, Fe3(P2O7)2, and a phase designated as Y-phase. The catalysts consisting of both Fe2+ and Fe3+ ions showed a higher activity than FePO4 and Fe2P2O7. During use in the reaction for more than 24 h, FePO4 was transformed to another unknown phase consisting of both Fe2+ and Fe3+ ions, which is designated here as M-phase. The best performances were obtained with the catalyst consisting of M-phase. The optimum oxygen feed rate to form the M-phase is in the range of 10 to 15 mmol/h, when the feed of lactic acid is 20 mmol/h. The M-phase was stable under the reaction conditions used and was not reoxidized by air even at 300°C.
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