溶剂化
电解质
水溶液
电化学
化学
电化学窗口
共晶体系
无机化学
化学工程
离子
有机化学
物理化学
离子电导率
电极
合金
工程类
作者
Leilei Li,Haoran Cheng,Shouxin Zhang,Yingjun Guo,Chunsheng Sun,Min Zhou,Qian Li,Zheng Ma,Jun Ming
出处
期刊:ACS energy letters
[American Chemical Society]
日期:2023-01-24
卷期号:8 (2): 1076-1095
被引量:50
标识
DOI:10.1021/acsenergylett.2c02585
摘要
Aqueous electrolyte design is pivotal for boosting the energy density and lifespan of aqueous batteries, because it can expand the electrochemical stability window and also mitigate the parasitic side reactions. Until now, three main kinds of electrolytes, i.e., water-in-salt, eutectic, and additives-modified electrolytes, have been developed by which the activity of H2O can be lowered and/or the formed specific solid–electrolyte interphase (SEI) can mitigate the decomposition of H2O. However, there is still a lack of a universal model to elucidate the reason for the improved performance, especially as the SEI interpretation becomes ever more controversial. Herein, we present a quantitative and graphical model of the electrolyte solvation structure and metal-ion (de)solvation process (i.e., interfacial model) to summarize a relationship between the electrolyte–electrode interfacial chemistry and electrode performance. This Focus Review extends the solvation structure and interfacial model into the field of aqueous electrolytes, revealing the essential influence of the solvation structure's properties on electrolyte stability and electrode performance, by which electrode performance and electrolyte design can be more quantitatively and accurately understood.
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