三联烯
化学
硫醇
二硫键
部分
硫黄
产量(工程)
星团(航天器)
惰性气体
高分子化学
结晶学
立体化学
有机化学
生物化学
材料科学
计算机科学
冶金
程序设计语言
作者
Tomoya Fukui,Riku Saitou,Fumiaki Tomi,Shoichi Kubo,Atsushi Shishido,Takanori Fukushima
标识
DOI:10.1093/chemle/upae052
摘要
Abstract When a DMF solution of 1,8,13-trimercaptotriptycene is allowed to stand under an inert atmosphere, a single crystalline molecular cluster with disulfide bonding results. Likewise, several thiol-containing triptycene derivatives yield single crystalline disulfide-containing clusters with different structural patterns. One of these clusters featuring a densely arranged tetrapod-like disulfide moiety exhibits a particularly high refractive index of 1.75, much higher than that of the others, although the sulfur contents of these clusters are comparable.
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