亲爱的研友该休息了!由于当前在线用户较少,发布求助请尽量完整地填写文献信息,科研通机器人24小时在线,伴您度过漫漫科研夜!身体可是革命的本钱,早点休息,好梦!

Magnetic Induction Heating-Driven Flow Chemistry Enabling Uniform and Continuous Growth of Metal–Organic Frameworks in Confined Microchannels of Wood

感应加热 流量(数学) 纳米技术 金属有机骨架 连续流动 材料科学 化学 化学工程 机械 电磁线圈 物理 工程类 电气工程 有机化学 吸附
作者
Lianghui Wang,Xunan Shen,Yingle Tao,Haiqing Li
标识
DOI:10.1021/acsaenm.4c00048
摘要

Due to substantial mass transfer resistance and a lack of control over the solvothermal condition in the confined microchannels of wood, in situ growth of metal–organic frameworks (MOFs) in bulky wood is severely suppressed by existing synthetic approaches. This limitation results in the production of MOF-impregnated wood (MOF@wood) with uneven MOF distributions and extremely low MOF loadings, thereby significantly restricting their adsorption-associated applications. To address these challenges, a magnetic induction heating-driven flow chemistry (MHFC) strategy is developed for the synthesis of MOF@wood composites. In MHFC, the synergistic integration of both flow chemistry and localized magnetic induction heating (LMIH) chemistry effectively overcomes the mass transfer resistance of MOF mother liquors and encourages selective growth of MOF crystals in the confined microchannels of wood, regardless of wood length. In comparison to traditional synthetic strategies, MOF@wood produced using MHFC demonstrates vastly improved MOF distributions and up to around 4 times higher MOF loadings, exceptional LMIH capability, and well-defined shapes. Notably, the formation of free MOF crystals as side products in the effluent is significantly suppressed. Taking HKUST-1@wood as an example, the resulting composites exhibit a CO2 adsorption capacity of up to 45.4 cm3 g–1 at 298 K and a regeneration efficiency of 100% driven by LMIH, underscoring the tremendous potentials of MOF@wood in adsorption-associated applications. Therefore, MHFC not only presents an all-encompassing solution to the challenges posed by existing strategies for MOF@wood synthesis but also showcases a promising approach to significantly enhance the in situ growth of functional materials within the confined spaces of large host structures.
最长约 10秒,即可获得该文献文件

科研通智能强力驱动
Strongly Powered by AbleSci AI
更新
PDF的下载单位、IP信息已删除 (2025-6-4)

科研通是完全免费的文献互助平台,具备全网最快的应助速度,最高的求助完成率。 对每一个文献求助,科研通都将尽心尽力,给求助人一个满意的交代。
实时播报
所所应助科研通管家采纳,获得10
3秒前
科研通AI2S应助科研通管家采纳,获得10
3秒前
喜悦幻灵完成签到 ,获得积分10
5秒前
10秒前
热心易绿完成签到 ,获得积分10
12秒前
丰富莹芝完成签到,获得积分10
34秒前
38秒前
57秒前
cherlie应助Plum22采纳,获得20
59秒前
edisonyan完成签到 ,获得积分10
59秒前
刘宇童发布了新的文献求助10
1分钟前
1分钟前
大个应助刘宇童采纳,获得10
1分钟前
小二郎应助xiongdi521采纳,获得10
1分钟前
1分钟前
xiongdi521发布了新的文献求助10
1分钟前
1分钟前
1分钟前
Ava应助吕易巧采纳,获得10
2分钟前
2分钟前
2分钟前
andrele发布了新的文献求助10
2分钟前
2分钟前
吕易巧发布了新的文献求助10
2分钟前
2分钟前
2分钟前
2分钟前
2分钟前
3分钟前
Microbiota完成签到,获得积分10
3分钟前
会飞的流氓兔完成签到 ,获得积分10
3分钟前
3分钟前
DL完成签到,获得积分10
3分钟前
DL发布了新的文献求助10
3分钟前
小马甲应助科研通管家采纳,获得10
4分钟前
MchemG应助科研通管家采纳,获得100
4分钟前
大模型应助科研通管家采纳,获得10
4分钟前
李健的小迷弟应助xiongdi521采纳,获得10
4分钟前
4分钟前
闫雪发布了新的文献求助10
4分钟前
高分求助中
The Mother of All Tableaux: Order, Equivalence, and Geometry in the Large-scale Structure of Optimality Theory 3000
A new approach to the extrapolation of accelerated life test data 1000
ACSM’s Guidelines for Exercise Testing and Prescription, 12th edition 500
Indomethacinのヒトにおける経皮吸収 400
Phylogenetic study of the order Polydesmida (Myriapoda: Diplopoda) 370
基于可调谐半导体激光吸收光谱技术泄漏气体检测系统的研究 350
Robot-supported joining of reinforcement textiles with one-sided sewing heads 320
热门求助领域 (近24小时)
化学 材料科学 医学 生物 工程类 有机化学 生物化学 物理 内科学 纳米技术 计算机科学 化学工程 复合材料 遗传学 基因 物理化学 催化作用 冶金 细胞生物学 免疫学
热门帖子
关注 科研通微信公众号,转发送积分 3990148
求助须知:如何正确求助?哪些是违规求助? 3532119
关于积分的说明 11256456
捐赠科研通 3271016
什么是DOI,文献DOI怎么找? 1805171
邀请新用户注册赠送积分活动 882288
科研通“疑难数据库(出版商)”最低求助积分说明 809228