双折射
各向异性
材料科学
GSM演进的增强数据速率
块(置换群论)
带隙
光电子学
光学
物理
计算机科学
电信
几何学
数学
作者
Lehui Liu,Feifei Yuan,Yisheng Huang,Zhoubin Lin,Lizhen Zhang
出处
期刊:Dalton Transactions
[The Royal Society of Chemistry]
日期:2023-01-01
卷期号:52 (17): 5798-5803
摘要
The [B3O6] group has attracted a lot of attention as α-BaB2O4 (α-BBO) is composed of the [B3O6] group showing a short UV cut-off edge and a large birefringence. However, it is difficult to synthesize novel crystals with properties beyond α-BBO using [B3O6] as a fundamental building block (FBB). Hence, we successfully synthesized two cases of α-BBO-type organic-inorganic hybrid compounds using α-BBO as the template and melamine [C3N6H6] as the fundamental building block. The coplanar and parallel arrangement of π-conjugated [C3N6H6] groups makes them exhibit excellent optical properties, including improved birefringence responses (0.264 and 0.243@546 nm) and wide bandgaps (4.12 and 4.20 eV).
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