材料科学
热能储存
相变材料
热稳定性
化学工程
界面聚合
肺表面活性物质
熔点
三聚氰胺树脂
聚合
高能材料
潜热
热的
复合材料
化学
有机化学
爆炸物
聚合物
热力学
单体
物理
工程类
涂层
作者
Veerakumar Chinnasamy,Jaehyeok Heo,Hoseong Lee,Yongseok Jeon,Honghyun Cho
标识
DOI:10.1016/j.aej.2023.03.085
摘要
This study discusses the preparation and thermophysical characterization of microencapsulated stearyl alcohol (SA) for thermal energy storage and heat transportation applications. The developed microcapsules consist of SA, an organic phase change material (PCM) core material, and melamine formaldehyde (MF) shell material. The PCM microcapsules have been synthesized using sodium dodecyl sulfate as a surfactant using an in-situ polymerization technique and subjected to various thermal and structural characterization techniques. The results revealed that prepared microencapsulated PCM (MPCM) with 0.25 g of surfactant and 5 g of PCM exhibits better morphological structure with an average diameter of 4.7 µm. The onset melting point and latent heat were estimated as 42 °C and 137.7 Jg−1, respectively. The highest encapsulation ratio of 51.9 % and 52.3 % were observed for the core to the shell ratio of 5:8.4. The MPCMs are thermally stable and the decomposition temperature of the MPCM was higher than the pure PCM. The developed MPCM shows good chemical stability and no leakage during the phase change process. The obtained results elucidate the suitability of the developed MPCM in thermal energy storage applications.
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