Uniform and oriented zinc deposition induced by artificial Nb2O5 Layer for highly reversible Zn anode in aqueous zinc ion batteries

材料科学 阳极 水溶液 化学工程 阴极 涂层 金属 图层(电子) 电偶阳极 原子层沉积 无机化学 纳米技术 冶金 电极 阴极保护 物理化学 化学 工程类
作者
Seongjoon So,Yong Nam Ahn,Jae-Wook Ko,Il Tae Kim,Jaehyun Hur
出处
期刊:Energy Storage Materials [Elsevier BV]
卷期号:52: 40-51 被引量:112
标识
DOI:10.1016/j.ensm.2022.07.036
摘要

• Nb 2 O 5 artificial film is coated on Zn metal via a facile spin-coating process. • High dielectric constant of Nb 2 O 5 promotes homogeneous Zn-ion flux. • Various in-situ analyses confirm uniform Zn electrodeposition behavior with Nb 2 O 5 . • Nb 2 O 5 @Zn anode shows good full cell performance with VO 2 cathode. Zn metal has recently emerged as a promising candidate for stable and reversible anode in aqueous rechargeable batteries. However, despite the high reversibility of Zn metal in aqueous media, Zn metal anode utilization is limited owing to unavoidable dilemmas, such as dendrite growth, hydrogen gas evolution, and “dead Zn”, eventually leading to battery breakdown. Herein, we propose a Nb 2 O 5 film as an effective coating layer to guarantee uniform ion flux and a rapid transportation pathway for Zn ions through Maxwell–Wagner polarization, resulting in homogeneous Zn electrodeposition under the Nb 2 O 5 layer. The artificial Nb 2 O 5 layer coated on the Zn surface (Nb 2 O 5 @Zn) acted as a guide for Zn deposition, enabling a dense and uniform morphology of electrodeposited Zn oriented in a specific direction. The symmetric Nb 2 O 5 @Zn anode system exhibited stable plating/stripping for up to 1000 h. Outstanding durability and resilience (220 h at 5 mA cm −2 /5 mAh cm −2 ) and rapid plating/stripping with excellent recovery (returning to 1 from 10 mA cm −2 ) were verified under harsh cycling conditions. The excellent characteristics of Nb 2 O 5 layer resulted in high electrochemical stability and performance for a full cell with a VO 2 cathode for practical applications. A highly reversible Zn ion aqueous battery was demonstrated by thin Nb 2 O 5 layer coating on Zn metal anode. An artificial Nb 2 O 5 layer effectively suppressed preferential Zn dendrite growth and hydrogen evolution reaction and facilitated Zn ion transport for homogenous Zn electrodeposition. As such, the Zn ion battery with proposed method exhibited an outstanding electrochemical performance over a wide range of cycling conditions.
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