Multifunctional microwave absorption materials of multiscale cobalt sulfide/diatoms co-doped carbon aerogel

Microwave absorption materials (MAMs) have attracted much attention for their potential applications in stealth technology and prevention of electromagnetic pollution problems. Multifunctional MAMs are highly demanded because they can be applied in harsh environments. Hence, based on multiscale manipulation of atomic engineering, nanostructure and microstructure, a multiscale hollow cobalt sulfide/diatoms co-doped carbon aerogel was preparedthrough the physical crosslinking of divalent ions, unidirectional freezing, kirkendall effect, and heteroatomic doping. The aerogel with a low density of 13.1 mg/mm3 has a unique “lamellar-pillar” network structure due to the growth of ice crystals during the preparation process. With the assistance of thiourea, the doping of N, S atoms and the construction of hollow cobalt sulfide are accomplished simultaneously. The ingenious integration facilitates the synergistic effect of conductive loss, defect polarization, interfacial polarization, and multiple scattering. The multiscale hollow cobalt sulfide/diatoms co-doped carbon aerogel had a maximum reflection loss of −51.96 dB and an effective absorption bandwidth of 6.4 GHz, which is higher than that of other reported MAMs. It is further verified through finite element simulation and experiments that the aerogel has an excellent microwave absorption properties. In addition, the aerogel has excellent thermal insulation and flame retardant properties. Therefore, the development of this aerogel can help to use MAMs in complex applications.