Structural and functional perspectives of carbon filter media in constructed wetlands for pollutants abatement from wastewater

Constructed wetlands (CWs) represent the most viable artificial wastewater treatment system that works on the principles of natural wetlands. Filter media are integrally linked to CWs and have substantial impacts on their performance for pollutant removal. Carbon-derived substrates have been in the spotlight for decades due to their abundance, sustainability, reusability, and potential to treat complex contaminants. However, the efficiency and feasibility of carbon substrates have not been fully explored, and there are only a few studies that have rigorously analyzed their performance for wastewater treatment. This critical synthesis of the literature review offers comprehensive insights into the utilization of carbon-derived substrates in the context of pollutant removal, intending to enhance the efficiency and sustainability of CWs. It also compares several carbon-based substrates with non-carbon substrates with respect to physiochemical properties, pollutant removal efficiency, and cost-benefit analysis. Furthermore, it addresses the concerns and possible remedies about carbon filtration materials such as configuration, clogging minimization, modification, and reusability to improve the efficacy of substrates and CWs. Recommendations made to address these challenges include pretreatment of wastewater, use of a substrate with smaller pore size, incorporation of multiple filter media, the introduction of earthworms, and cultivation of plants. A current scientific scenario has been presented for identifying the research gaps to investigate the functional mechanisms of modified carbon substrates and their interaction with other CW components.