电解质
烧结
材料科学
兴奋剂
离子电导率
电导率
金属
陶瓷
相(物质)
分析化学(期刊)
物理
结晶学
凝聚态物理
冶金
化学
量子力学
电极
色谱法
作者
Jie Yang,Dong Li,Lingbo Shao,Qing Wei,Guangchao Qin,Changan Tian
标识
DOI:10.1142/s1793604723500194
摘要
La 2 Mo 2 O 9 doped with cheap metal cations can further increase their conductivity. The transition metal element Mn and the rare-earth element Y co-doped La 2 Mo 2 O 9 -based electrolyte was used, and the sintered ceramic body La[Formula: see text]Y[Formula: see text]Mo [Formula: see text][Formula: see text]Mn[Formula: see text]O [Formula: see text][Formula: see text]([Formula: see text]= 0[Formula: see text]0.4) was prepared by the sol-gel method, sintering at 950°C. The results show that the samples can suppress the phase transition and retain the [Formula: see text]-phase of the structure of La 2 Mo 2 O 9 , due to doping, and it is a single pure phase, which has good sintering performance. Among them, La[Formula: see text]Y [Formula: see text]Mo[Formula: see text]Mn[Formula: see text]O[Formula: see text] reached the maximum ionic conductivity of 0.0292 S⋅cm[Formula: see text] at 800°C, and Ea is 0.425 eV, which can become a solid electrolyte material of IT-SOFC.
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