Controlled preparation of cobalt carbonate hydroxide@nickel aluminum layered double hydroxide core–shell heterostructure for advanced supercapacitors

Herein, we report the rational fabrication of unique core-shell nanoclusters composed of cobalt carbonate hydroxide (Co-CH) @ nickel aluminum layered double hydroxide (NiAl-LDH) on a carbon cloth (CC) substrate using a two-step hydrothermal strategy. The one-dimensional (1D) Co-CH nanowires core-shell functions as a framework for the growth of two-dimensional (2D) NiAl-LDH nanosheets, leading to the formation of a hierarchically porous core-shell heterostructure. The presence of abundant heterointerfaces enhances electrical conductivity, reduces charge transfer resistance, and facilitates ion/electron transfer. Taking full advantage of its unique nanostructure and synergistic effect of two components, the as-prepared Co-CH@NiAl-LDH hybrid material illustrates a specific capacity of 1029.4 C/g (2058.9 mC cm-2) at 1 A g-1 and good rate capability with a capacity retention of 68.5% at 20 A g-1. Additionally, the assembled Co-CH@NiAl-LDH//pine pollen-derived porous carbon (PPC) hybrid supercapacitor (HSC) delivers impressive energy and power densities of 66.2 Wh kg-1 (0.27 Wh cm-2) and 17529.7 Wh kg-1 (0.11 Wh cm-2), respectively. This device also achieves a superior capacity retention of 80.3% over 20,000 cycles. These findings prove the importance of engineering heterointerfaces in heterostructure for the promotion of energy storage performance.