The Cyclic 48-Tungsto-8-Phosphate [H7P8W48O184]33- Contant-Tézé Polyanion and Its Derivatives [H6P4W24O94]18- and [H2P2W12O48]12-: Structural Aspects And Reactivity

Polyoxometalates (POMs) are discrete, anionic metal-oxo clusters of early transition metals in high oxidation states (e.g., WVI, MoVI, VV) usually comprised of edge- and corner-shared MO6 octahedra. Lacunary POMs are...