Polarity of Ordered Solvent Molecules in 9,9′-Bianthracene Single Crystals Selects between Singlet Fission or Symmetry-Breaking Charge Separation

Singlet exciton fission (SF) and symmetry-breaking charge separation (SB-CS) are both photophysical processes that can occur between two organic chromophores and are both of interest to improve solar energy conversion. Here, we tuned the photophysics of a 9,9'-bianthracene (