Fe(OTf)3 and γ-Cyclodextrin Catalyzed Hydroarylation of Alkenes with 1-Naphthols and 2-Naphthols

Abstract A Fe(OTf)3 and γ-cyclodextrin-catalyzed hydroarylation of alkenes with 1-naphthols or 2-naphthols is demonstrated. This efficient and general method delivers a wide range of benzylic naphthols from readily available starting materials with high chemo- and regioselectivity in up to 99% yield, with no need for a strong base or additive.