碳负离子
化学
电泳剂
小学(天文学)
分子内力
药物化学
自由基离子
光催化
组合化学
有机化学
光化学
催化作用
离子
光催化
物理
天文
作者
Austin D. Marchese,Julia R. Dorsheimer,Tomislav Rovis
标识
DOI:10.1002/anie.202317563
摘要
A method for the generation of tertiary carbanions via a deaminative radical-polar crossover is reported using redox active imines from α-tertiary primary amines. A variety of benzylic amines and amino esters can be used in this approach, with the latter engaging in a novel "aza-Reformatsky" reaction. Electronic trends correlate the stability of the resulting carbanion with reaction efficiency. The anions can be trapped with different electrophiles including aldehydes, ketones, imines, Michael acceptors, and H
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