材料科学
热电效应
散射
凝聚态物理
热电材料
热导率
中子衍射
声子散射
声子
衍射
塞贝克系数
热传导
晶体结构
结晶学
光学
物理
热力学
化学
复合材料
作者
Jinfeng Dong,Lei Hu,Jue Liu,Yukun Liu,Yilin Jiang,Zhiling Yu,Xian Yi Tan,Ady Suwardi,Qiang Zheng,Qian Li,Jing‐Feng Li,Vinayak P. Dravid,Qingyu Yan,Mercouri G. Kanatzidis
标识
DOI:10.1002/adfm.202314499
摘要
Abstract The crystal structure and transport properties of GeBi 2 Te 4 are investigated as a layered compound with potential applications as thermoelectric materials. A disordered arrangement of Ge and Bi atoms in a septuple‐layer structure is discovered through synchrotron radiation X‐ray diffraction and transmission electron microscopy. Neutron pair distribution function analysis revealed the presence of discordant Ge atoms with an off‐centering distance of 0.12 Å at 300 K. The thermal conductivity of GeBi 2 Te 4 is very low due to the strong phonon scattering. This is a result of the three Einstein local oscillators coupled with the disordered arrangement of atoms. This study also explores further the structural characteristics of these materials and their associated phonon scattering processes. The effect of Sb substitution for Ge on the electrical transport properties of the sample is profound, resulting in a change from p‐type to n‐type conduction. An enhanced thermoelectric figure of merit ( ZT ) of 0.45 at 523 K in the in‐plane direction is obtained. This research provides valuable insights into the crystal structure and transport properties of GeBi 2 Te 4 , showcasing its promising role as a thermoelectric material with potential for near‐room‐temperature applications.
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