光催化
材料科学
金红石
石墨氮化碳
氮化碳
二氧化钛
异质结
碳纤维
氮化物
分解水
制氢
化学工程
氢
纳米技术
复合材料
复合数
催化作用
化学
图层(电子)
光电子学
有机化学
工程类
作者
Jianxin Li,H. Wang,Haixiang Song,Yao Guo,Shuaishuai Hu,Huibin Zheng,Shiding Zhang,Xianchang Li,Qianqian Gao,Chengbo Li,Zunwei Zhu,Yitong Wang
标识
DOI:10.1007/s42114-023-00659-8
摘要
Photocatalysis technology is one of the hotspots in recent years to solve a series of social problems such as energy crisis and environmental pollution. It is an important way to improve the photocatalytic efficiency by constructing heterojunction and improving the utilization rate of sunlight. In this paper, nitrogen-doped rutile titania and graphite phase carbon nitride composites were synthesized successfully. Although nitrogen-doped rutile titanium dioxide cannot meet the thermodynamic conditions of hydrogen production, the photocatalytic hydrogen production rate of nitrogen-doped rutile titania/graphitic carbon nitride composite reaches to 2121.9 μmol h−1 g−1, which is 2.57 times higher than that of the pristine graphitic carbon nitride. By means of density functional theory, the band structure, state density, work function, differential charge density, and Bader charge distribution of the samples were analyzed. It was revealed that the Z-scheme heterojunction formed at the carbon nitride interface of nitrogen-doped rutile titanium dioxide/graphite carbon nitride effectively promoted the improvement of photocatalytic performance. This study provides a feasible idea for the design and popularization of new cheap photocatalysts in the field of renewable energy.
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