二硒醚
化学
试剂
电化学
锰
二苯基二硒醚
组合化学
硼酸
有机化学
硒
电极
物理化学
作者
Ziyue Chen,Yuan Wang,Chenjian Hu,Daoxin Wang,Peilin Lei,Hong Yi,Yong Yuan,Aiwen Lei
出处
期刊:Organic Letters
[American Chemical Society]
日期:2022-04-29
卷期号:24 (18): 3307-3312
被引量:28
标识
DOI:10.1021/acs.orglett.2c00607
摘要
A powerful and environmentally friendly electrochemical manganese-promoted free radical selenylation reaction between boronic acids and diselenide reagents was established. This electrochemical protocol provides a practically applicable way to a series of valuable organoselenium compounds with the use of easy available materials. Mechanistic experiments implied that the seleno-radical formed via direct or indirect electrochemical oxidation of diselenide may be involved as a key species in this transformation.
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