环氧化大豆油
大豆油
催化作用
材料科学
润湿
涂层
反应条件
原材料
化学工程
丙烯酸
复配
复合材料
化学
有机化学
共聚物
聚合物
工程类
食品科学
作者
Xiao Chu,Shao Jie Liu,Feng Qing Zhao
出处
期刊:Applied Mechanics and Materials
[Trans Tech Publications, Ltd.]
日期:2014-10-01
卷期号:662: 7-10
被引量:9
标识
DOI:10.4028/www.scientific.net/amm.662.7
摘要
In this paper, a kind of abundant and environment-friendly material—epoxidized soybean oil (ESO) was chosen to be esterified with acrylic acid to produce acrylated epoxidized soybean oil (AESO). By studying the influence of various factors including feed rate, reaction temperature, feed ratio, catalyst and inhibitor on the reaction, we got the optimal synthesis conditions: feed ratio is 1.25:1; reaction temperature is 120 °C; feeding time is about 2.5h;the dosage of the inhibitor (TBC) is 0.15 % and the catalyst (Triphenylphosphine oxide) is 1.5 %. The AESO we prepared has low viscosity, low skin irritation, excellent pigment wetting characteristics and so on. It can also be widely used in the manufacture of coating, printing ink, paint, etc.
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