Polypyrrole/Graphene/Polyaniline Ternary Nanocomposite with High Thermoelectric Power Factor

Polypyrrole/Graphene/Polyaniline (PPy/GNs/PANi) ternary nanocomposite with high thermoelectric power factor has been successfully prepared through the combination of in situ polymerization and solution process. FTIR, Raman spectra, XRD, and SEM analyses show the strong π–π interactions existed among PPy, GNs, and PANi, leading to the formation of more ordered regions in the composite. Both the in situ polymerization and solution process can enhance the dispersion homogeneity of graphene in the polymer matrix, bringing about increased nanointerfaces in the PPy/GNs/PANi composite. The thermoelectric properties of Polypyrrole/Graphene (PPy/GNs), Polyaniline/Graphene (PANi/GNs), and PPy/GNs/PANi composites are measured at different temperatures after being cold pressed. Consequently, the PPy/GNs/PANi composite with 32 wt % graphene demonstrates optimal electrical conductivity, Seebeck coefficient and extremely high power factor of up to 52.5 μ W m–1 K–2, which is almost 1.6 × 103 times, 1.4 × 103 times, 2.7 times, and 3.6 times higher than those of the pure PANi, pure PPy, PPy/GNs composite, and PANi/GNs composite, respectively.