旋转交叉
铁质
铁
化学
联苯
离子
结晶学
材料科学
无机化学
有机化学
聚合物
亚苯基
作者
Leoní A. Barrios,Rosa Diego,Mohanad Darawsheh,Jesús I. Martínez,Olivier Roubeau,Guillem Aromı́
摘要
A designed dimetallic Fe(II) helicate made with biphenylene-bridged bispyrazolylpyridine ligands and exhibiting a process of spin crossover at temperatures above ambient is shown to encapsulate an S = 5/2 tris-oxalato Fe(III) ion. The spin relaxation dynamics of this guest are strongly reduced upon encapsulation.
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