Passive Air Sampling of Polychlorinated Biphenyls and Organochlorine Pesticides at the Korean Arctic and Antarctic Research Stations: Implications for Long-Range Transport and Local Pollution

To assess levels and patterns of polychlorinated biphenyls (PCBs) and organochlorine pesticides (OCPs) in polar regions, XAD-resin based passive air samplers were deployed for one year at the Korean polar research stations at Ny-Ålesund, Norway (2005−2006) and King George Island, Antarctica (2004−2005). Backward trajectories suggest that these stations are affected by long-range transport from source regions in Northern Europe and Russia and the southern tip of South America, respectively. Relatively high levels of PCB-11, averaging 60 pg·m−3, were observed in Antarctica, suggesting an unusual source of PCB-11 to the Southern Hemisphere. Reflecting the hemispheric distribution of global PCB emissions, the average level of Σ205PCB (excluding three mono-CBs and PCB-11) was five times higher in the Arctic (95 pg·m−3) than in the Antarctic (19 pg·m−3). Levels of Σ9PCB at Ny-Ålesund were similar to those reported for other Arctic sites, while levels at King George Island were lower than at other sites on the Antarctic Peninsula but 1 order of magnitude higher than background levels measured at a more remote Antarctic site. Light homologues were predominant in all samples (except for one Arctic sample), consistent with the hypothesis of global fractionation and predictions of long-range transport potential. Dominance of heavy PCBs on the roof of the main building at Ny-Ålesund and a concentration gradient with distance from the main building at King George Island strongly indicated the influence of local sources. OCP levels were also influenced by long-range transport but not by local sources. This study highlights the feasibility of using passive air sampling to assess both long-range transport and local pollution in remote regions.