纳米复合材料
材料科学
极限抗拉强度
硅橡胶
抗撕裂性
复合材料
表面改性
硅酮
傅里叶变换红外光谱
纳米颗粒
硅烷
天然橡胶
气相二氧化硅
化学工程
纳米技术
工程类
作者
Fahui Yan,Xiaobing Zhang,Feng Liu,LI Xiao-hong,Zhijun Zhang
标识
DOI:10.1016/j.compositesb.2015.01.030
摘要
A series of nanosilica (denoted as nano-SiO2) surface-capped with organic modifiers hexamethyldisilazane (denoted as HMDS; molecular formula: C6H19NSi2) and KH570 (molecular formula: C10H20O5Si) containing CC double bond were prepared by in situ surface-modification method. As-obtained nano-SiO2 particles were characterized by Fourier transform infrared spectrometry and transmission electron microscopy, and they were also used to reinforce silicone rubber (denoted as SR) in order to improve the mechanical properties. Moreover, a universal material testing machine was performed to determine the mechanical properties of the SR-matrix nanocomposites. Results showed that the surface properties of nano-SiO2 can be adjusted by changing the ratio of these modifiers. The tensile strength, tear strength and elongation at break of nano-SiO2/SR nanocomposites are comparable to or even better than those of R-106/SR nanocomposite (R-106 refers to commercially obtained fumed SiO2 nanoparticles that was modified with silane coupling agent). The mechanical strength of nano-SiO2/SR nanocomposites especially for tear strength largely improve with adding a small amount of CC content of the surface-capped nano-SiO2. More importantly, it could be feasible to manipulate the mechanical properties of silicone rubber by properly adjusting the dosages of surface-modifiers HMDS and KH570 during the preparation of in situ surface-capped nanosilica, which could be of special significance to developing high performance SR-matrix nanocomposites.
科研通智能强力驱动
Strongly Powered by AbleSci AI