荧光粉
钇
铈
分析化学(期刊)
化学
核化学
发光
X射线光电子能谱
材料科学
无机化学
物理
色谱法
核磁共振
氧化物
光电子学
有机化学
作者
Lianming Wang,Liqiang Zhuang,Hao Xin,Yuexia Huang,Deqiang Wang
出处
期刊:Open journal of inorganic chemistry
[Scientific Research Publishing, Inc.]
日期:2015-01-01
卷期号:05 (01): 12-18
被引量:36
标识
DOI:10.4236/ojic.2015.51003
摘要
In order to confirm the relationship between the luminescence and the ratio of Ce3+/Ce4+ more clearly, a series of YAG:Ce3+ (Yttrium Aluminum Garnet, Y2.94Al5O12:0.06Ce3+) phosphors were pre- pared under different sintering atmosphere. A semi-quantitative analysis based on X-ray photoe-lectron spectroscopy (XPS) was introduced to study the mole ratio of Ce3+/Ce4+ in the as-synthesized YAG:Ce3+ phosphors. The results indicated that the percentage of Ce3+/(Ce3+ + Ce4+) reached 88.46% under the reduction atmosphere. The emission intensity of YAG:Ce3+ phosphors was in-creased significantly with the increasing of Ce3+ concentration.
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