校准
氮氧化物
一氧化碳
线性回归
环境科学
化学
计算机科学
统计
数学
氮氧化物
机器学习
生物化学
燃烧
催化作用
有机化学
作者
Laurent Spinelle,Michel Gerboles,Maria Gabriella Villani,M. Aleixandre,Fausto Bonavitacola
标识
DOI:10.1016/j.snb.2016.07.036
摘要
In this work the performances of several field calibration methods for low-cost sensors, including linear/multi linear regression and supervised learning techniques, are compared. A cluster of either metal oxide or electrochemical sensors for nitrogen monoxide and carbon monoxide together with miniaturized infra-red carbon dioxide sensors was operated. Calibration was carried out during the two first weeks of evaluation against reference measurements. The accuracy of each regression method was evaluated on a five months field experiment at a semi-rural site using different indicators and techniques: orthogonal regression, target diagram, measurement uncertainty and drifts over time of sensor predictions. In addition to the analyses for ozone and nitrogen oxide already published in Part A [1], this work assessed if carbon monoxide sensors can reach the Data Quality Objective (DQOs) of 25% of uncertainty set in the European Air Quality Directive for indicative methods. As for ozone and nitrogen oxide, it was found for NO, CO and CO2 that the best agreement between sensors and reference measurements was observed for supervised learning techniques compared to linear and multilinear regression.
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