All-Visible-Light-Activated Diarylethene Photoswitches

二芳基乙烯 光致变色 可见光谱 光化学 材料科学 紫外线 纳米技术 光电开关 光电子学 化学
作者
Ruiji Li,Ting Ou,Wen Li,Yehao Yan,Wei Li,X.‐Z. QIN,Shouxin Wang
出处
期刊:Molecules [MDPI AG]
卷期号:29 (21): 5202-5202
标识
DOI:10.3390/molecules29215202
摘要

Photochromic compounds have attracted much attention for their potential applications in photo-actuators, optoelectronic devices and optical recording techniques. This interest is driven by their key photochemical and photophysical properties, which can be reversibly modulated by light irradiation. Among them, diarylethene compounds have garnered extensive investigation due to their excellent thermal stability of both open- and closed-form isomers, robust fatigue resistance, high photocyclization quantum yield and good photochromic performance in both solution and solid phases. However, a notable limitation in expanding the utility of diarylethene compounds is the necessity for ultraviolet light to induce their photochromism. This requirement poses challenges, as ultraviolet light can be detrimental to biological tissues, and its penetration is often restricted in various media. This review provides an overview of design strategies employed in the development of visible-light-responsive diarylethene compounds. These design strategies serve as a guideline for molecular design, with the potential to significantly broaden the applications of all-visible-light-activated diarylethene compounds in the realms of materials science and biomedical science.
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