加氢脱氧
双功能
催化作用
硅酸铝
金属
化学
无机化学
有机化学
选择性
作者
James A. Hunns,Lee J. Durndell,Xingguang Zhang,Muxina Konarova,Adam F. Lee,Karen Wilson
标识
DOI:10.1021/acscatal.4c00402
摘要
Strong synergy between proximate Bro̷nsted acid and metal sites over a Pt/amorphous silica–alumina (ASA) catalyst confers striking activity and selectivity enhancements for m-cresol hydrodeoxygenation to methylcyclohexane, a fuel additive and potential liquid organic hydrogen carrier for storing renewable energy. Molecular shuttling back and forth between cooperative acid and metal sites activates m-cresol for consecutive tautomerization, ring hydrogenation, and dehydration, ensuing eventual hydrogenation to methylcyclohexane with a fourfold yield enhancement compared to a physical mix of solid acid and Pt/SiO2.
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