Beryllium carbonyl Be(CO)n (n = 1–4) complex: a p-orbital analogy of Dewar–Chatt–Duncanson model

Transition metal-carbonyl bonds are rationalized by M ← CO σ donation and M → CO π back donation where the d orbital of the transition metal is involved. This bonding model provided by Dewar, Chatt and Duncanson (DCD) has rationalized many transition metal-ligand bonds. The involvement of p orbital in such a DCD model can be intriguing. Alkaline earth metals with ns