Rapid urbanization and industrialization can lead to the accumulation of toxic halogenated organic pollutants (HOPs) in soil environments, which poses a risk to the wider eco-environment. In this study, we explored the occurrence and health risks of halogenated organic pollutants by analysing surface soil samples (n = 209) collected from various E-waste dismantling, industrialized and urban areas, rural areas and remote areas in Zhejiang Province, China. The mean average concentrations (d.w.) and range (min–max) of the HOPs were Dechlorane plus (DP) = 0.14 ng/g (below detection limit (
industrialized and urban areas > rural areas > remote areas. Nevertheless, we observed high detection ratios in rural and remote areas, indicating scattered industrialization led to ubiquitous HOP soil pollution in the region.