Pulsed corona discharge: an advanced treatment method for antibiotic-contaminated water

化学 降级(电信) 污染 四氯乙烯 水处理 水解 电晕放电 污染物 环境化学 有机化学 环境工程 环境科学 生物 物理化学 电信 计算机科学 三氯乙烯 生态学 电极
作者
Florin Bilea,Corina Bradu,Andrei Medvedovici,Dunpin Hong,Monica Măgureanu
出处
期刊:Journal of Physics D [IOP Publishing]
卷期号:57 (43): 435205-435205
标识
DOI:10.1088/1361-6463/ad6882
摘要

Abstract Water pollution is one of the most significant problems of the current century. With the increase in medicine availability and use, pharmaceutical pollutants such as antibiotics become more prevalent in natural environments with potentially negative impact. In this study, a pulsed corona discharge was investigated as a possible treatment method of water contaminated with amoxicillin (AMX). Two system configurations were used: plasma and plasma-ozonation. In order to better grasp the effect of system and water matrix on degradation, different pulse widths, solutions pH and conductivity values, as well as the nature of the dissolved salts were investigated. Decreasing the pulse width from 300 ns to 106 ns (full width at half maximum) led to almost a two-fold increase in energy yield at 50% pollutant removal, and the addition of the ozonation reactor resulted six times enhancement in efficiency. While the water matrix had little impact on AMX degradation, the buffering capacity of carbonates has proven beneficial by preventing pH decrease during treatment. Under optimum conditions, the energy yield was 57 g kWh −1 at 93% removal of AMX in tap water. A number of 26 potential degradation products have been identified, resulting from hydroxylation of the benzene ring, oxidation of the thioester and amine groups, hydrolysis, and cleavage of the benzene, β -lactam and thiazole rings, along with fragmentation of the resulting compounds. All but seven degradation intermediates are completely removed by extending treatment duration to 60 min and the persistent ones are less toxic than the parent compound.
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