近程
催化作用
甲烷化
化学
质子交换膜燃料电池
钌
金属
纳米颗粒
化学工程
无机化学
一氧化碳
有机化学
工程类
作者
Peipei Wu,Shuaishuai Lyu,Ye Tian,Dongyue Zhao,Jingwei Ye,Mengni She,Song Song,Tao Ding,Xingang Li
标识
DOI:10.1016/j.cej.2023.146051
摘要
Preferential oxidation of CO (CO-PROX) is promising to purify H2 resources for proton-exchange membrane fuel cells with the challenges of identifying active sites and developing efficient catalysts. Herein, we report the high CO-PROX performance of Ru/TiO2 catalysts prepared by chemical-reduction method. The kinetic results reveal that the CO-PROX mechanism over the Ru/TiO2 catalysts follows the Langmuir-Hinshelwood model. We discover that Ruδ+ sites are more active for O2 activation and CO oxidation, while Ru0 sites prefer CO methanation in CO-PROX. The enhanced metal–support interaction (MSI) induces the formation of flat Ru nanoparticles, thereby increasing the number of interfacial Ruδ+ sites. Especially, compared with the conventional catalyst prepared by conventional wetness impregnation method, the as-synthesized RuTi-CR-R200 catalyst with strengthened MSI exhibits about 27 and 13 times higher reaction rate and intrinsic activity, respectively, for CO-PROX. To the best of our knowledge, our catalyst surpasses the catalytic performance of the reported Ru-based catalysts, and achieves 100% CO conversion in the wide temperature range of 90–150 °C, as well as high stability.
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