过电位
电催化剂
析氧
钒
催化作用
材料科学
兴奋剂
贵金属
化学工程
制作
镍
过渡金属
金属
纳米技术
无机化学
化学
电极
电化学
物理化学
冶金
光电子学
有机化学
工程类
医学
替代医学
病理
作者
Yin Huang,Yaoyao Pan,Xiaoyu Huang,Guangzheng Xu,Xiuhua Wang
出处
期刊:Dalton Transactions
[The Royal Society of Chemistry]
日期:2023-01-01
卷期号:52 (32): 11297-11302
被引量:4
摘要
Finding effective and affordable non-noble metal catalysts is one of the most important yet difficult tasks because of the sluggish kinetics of the oxygen evolution reaction (OER). Therefore, we synthesized vanadium-doped CoFe PBA nanosheets on nickel foam in a single step to change the electronic structure with metal doping. The sheet structure facilitates charge transfer, while vanadium doping modifies the electronic structure to enhance the catalytic activity. With just a 229 mV overpotential needed in the OER reaction to reach 10 mA cm-2, the as-synthesised electrocatalyst demonstrates high electrocatalytic activity. The produced electrocatalyst can operate at a current density of 10 mA cm-2 for 12 h, and it displays outstanding stability even at a high OER current density of 100 mA cm-2 for 12 h. This study will contribute to the development of efficient and affordable non-noble metal-based electrocatalysts.
科研通智能强力驱动
Strongly Powered by AbleSci AI