锆
铜
金属有机骨架
配体(生物化学)
化学
材料科学
无机化学
物理化学
吸附
有机化学
生物化学
受体
作者
Nizami Israfilov,Leo M. Meyer,Shabnam Feyziyeva,Nathalie Kyritsakas‐Gruber,Benoît Louis,Jean‐Marc Planeix
标识
DOI:10.1016/j.jssc.2024.124582
摘要
In this study, the synthesis of a series of novel glyme-modified ligands and their corresponding copper and zirconium metal-organic frameworks (MOF) has been successfully realized. In addition, while using copper salts, it was possible to yield a water-stable MOF. Besides, the utilization of zirconium salts resulted in the formation of MOF exhibiting a UiO-68 type structure. The thorough characterization of these MOF was performed using Single Crystal X-ray Diffraction (SCXRD), Powder X-ray Diffraction (PXRD), Fourier Transform Infrared Spectroscopy (FT-IR), Scanning Electron Microscopy (SEM), Thermogravimetric Analysis (TGA) and nitrogen adsorption-desorption isotherms. Furthermore, the CO2 adsorption capacity of these MOF was also evaluated. Despite the significant differences in their crystalline networks, all MOF exhibited appreciable CO2 adsorption capacities, ranging from 0.6 to 1.3 mmol g−1 at ambient pressure and 0 °C.
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