Recent Advances in Pristine Iron Triad Metal–Organic Framework Cathodes for Alkali Metal‐Ion Batteries

Abstract Pristine iron triad metal–organic frameworks (MOFs), i.e., Fe‐MOFs, Co‐MOFs, Ni‐MOFs, and heterometallic iron triad MOFs, are utilized as versatile and promising cathodes for alkali metal‐ion batteries, owing to their distinctive structure characteristics, including modifiable and designable composition, multi‐electron redox‐active sites, exceptional porosity, and stable construction facilitating rapid ion diffusion. Notably, pristine iron triad MOFs cathodes have recently achieved significant milestones in electrochemical energy storage due to their exceptional electrochemical properties. Here, the recent advances in pristine iron triad MOFs cathodes for alkali metal‐ion batteries are summarized. The redox reaction mechanisms and essential strategies to boost the electrochemical behaviors in associated electrochemical energy storage devices are also explored. Furthermore, insights into the future prospects related to pristine iron triad MOFs cathodes for lithium‐ion, sodium‐ion, and potassium‐ion batteries are also delivered.